Calcium-Rich Steel Slag as a Reactive Capping Material: Effects on Hydraulic Conductivity and Nutrient Attenuation in Cohesive Intertidal Sediments

Abstract

Fine-grained intertidal sediments are typically characterized by low hydraulic conductivity and high nutrient loads, conditions that hinder biogeochemical recovery and exacerbate eutrophication. This study examined the feasibility of calcium-rich steel slag (SS) as a multifunctional capping material for improving both physical and chemical properties of cohesive sediments. Short-term (24 h) column experiments with two slag dosages (25 g and 50 g) revealed that the higher dosage (SS50) increased sediment hydraulic conductivity by 113.2%, likely through Ca2+-mediated flocculation and enhanced pore connectivity. Phosphate (PO4-P) in pore water decreased by up to 64.1%, and effluent dissolved inorganic nitrogen (DIN) declined by 62.8%, indicating combined effects of Ca-driven precipitation, adsorption, and enhanced flushing. However, SS addition also raised pore water pH (to 11.8) and lowered redox potential, leading to transient phosphate release at the effluent boundary under reducing conditions. Cation analysis confirmed Ca2+ stability and Na+ reduction, suggesting improved sediment structural integrity. The results suggest that steel slag is a promising reactive capping material capable of enhancing permeability and controlling nutrient release in cohesive coastal sediments, yet further investigation into long-term ecological effects and dosage optimization is necessary.

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