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The OceanFlux Greenhouse Gases methodology for deriving a sea surface climatology of CO 2 fugacity in support of air–sea gas flux studies

L. M. Goddijn-Murphy; D. K. Woolf; P. E. Land; J. D. Shutler; C. Donlon
Ocean Science · Vol. 11, Issue 4 · pp. 519-541 · 2015

Abstract

Climatologies, or long-term averages, of essential climate variables are useful for evaluating models and providing a baseline for studying anomalies. The Surface Ocean CO2 Atlas (SOCAT) has made millions of global underway sea surface measurements of CO2 publicly available, all in a uniform format and presented as fugacity, fCO2. As fCO2 is highly sensitive to temperature, the measurements are only valid for the instantaneous sea surface temperature (SST) that is measured concurrently with the in-water CO2 measurement. To create a climatology of fCO2 data suitable for calculating air–sea CO2 fluxes, it is therefore desirable to calculate fCO2 valid for a more consistent and averaged SST. This paper presents the OceanFlux Greenhouse Gases methodology for creating such a climatology. We recomputed SOCAT's fCO2 values for their respective measurement month and year using monthly composite SST data on a 1° × 1° grid from satellite Earth observation and then extrapolated the resulting fCO2 values to reference year 2010. The data were then spatially interpolated onto a 1° × 1° grid of the global oceans to produce 12 monthly fCO2 distributions for 2010, including the prediction errors of fCO2 produced by the spatial interpolation technique. The partial pressure of CO2 (pCO2) is also provided for those who prefer to use pCO2. The CO2 concentration difference between ocean and atmosphere is the thermodynamic driving force of the air–sea CO2 flux, and hence the presented fCO2 distributions can be used in air–sea gas flux calculations together with climatologies of other climate variables.

Bibliographic Information

JournalOcean Science
PublisherCopernicus Publications / European Geosciences Union
Publication Date2015-07-08
Publication Year2015
Volume11
Issue4
Pages519-541
Document TypeJournal Article
Print ISSN1812-0784
eISSN1812-0792
DOI10.5194/os-11-519-2015
SubjectOceanography; physical oceanography; chemical oceanography; biogeochemistry; ocean modelling

Access Information

NARA Access CoverageOA / free full text
Journal Homepagehttps://www.ocean-science.net/
Publisher PageOpen Publisher Page
This article is openly available from the publisher.