Abstract
Emissions from open crop straw burning (OCSB) during crop harvest have exerted considerable impacts on the air quality in China, but the quantitative evaluation of OCSB to air pollutants remains insufficient. In the study, the WRF-Chem model is used to quantitatively evaluate the impacts of OCSB on the air quality in Hunan, China from October 15 to 26, 2024. During the study episode, OCSB contributes 45.7% and 16.8% of the anthropogenic emission of organic carbon and non-methane volatile organic compounds, respectively. Model simulations show that OCSB emissions account for 2.8% of the maximum daily 8-hour average ozone (MDA8 O 3 ) concentration, but play a more substantial role in particulate pollution, contributing 25.6% to near-surface fine particulate matter levels. OCSB is an important organic aerosol (OA) source, increasing primary OA by 46.2% and secondary OA by 62.7%. The enhanced OA accounts for 54.8% of the total PM 2.5 increase induced by OCSB emissions. Sensitivity experiments show that the concentrations of aerosol species generally decrease linearly with reduced OCSB emissions, while MDA8 O 3 concentrations exhibit a non-linear trend due to the complex responses to its precursors. Implementing the clean disposal of straw residue during crop harvest presents an effective strategy to improve the air quality in Hunan.