Crystal structure and investigation of Bi2TeO6·nH2O (0 ≤ n ≤ $${\raise0.5ex\hbox{$\scriptstyle 2$} \kern-0.1em/\kern-0.15em \lower0.25ex\hbox{$\scriptstyle 3$}}$$): natural and synthetic montanite

Abstract

The crystal structure of montanite has been determined using single-crystal X-ray diffraction on a synthetic sample, supported by powder X-ray diffraction (PXRD), electron microprobe analysis (EPMA) and thermogravimetric analyses (TGA). Montanite was first described in 1868 as Bi 2 TeO 6 · n H 2 O ( n = 1 or 2). The determination of the crystal structure of synthetic montanite (refined composition Bi 2 TeO 6 ·0.22H 2 O) has led to the reassignment of the formula to Bi 2 TeO 6 · n H 2 O where 0 ≤ n ≤ $${\raise0.5ex\hbox{$\scriptstyle 2$} \kern-0.1em/\kern-0.15em \lower0.25ex\hbox{$\scriptstyle 3$}}$$ 2 / 3 rather than the commonly reported Bi 2 TeO 6 ·2H 2 O. This change has been accepted by the IMA–CNMNC, Proposal 22-A. The PXRD pattern simulated from the crystal structure of synthetic montanite is a satisfactory match for PXRD scans collected on both historical and recent natural samples, showing their equivalence. Two specimens attributed to the original discoverer of montanite (Frederick A. Genth) from the cotype localities (Highland Mining District, Montana and David Beck’s mine, North Carolina, USA) have been designated as neotypes. Montanite crystallises in space group P $$\overline{6 }$$ 6 ¯ , with the unit-cell parameters a = 9.1195(14) Å, c = 5.5694(8) Å, V = 401.13(14) Å 3 , and three formula units in the unit cell. The crystal structure of montanite is formed from a framework of BiO n and TeO 6 polyhedra. Half of the Bi 3+ and all of the Te 6+ cations are coordinated by six oxygen atoms in trigonal-prismatic arrangements (the first example of this configuration reported for Te 6+ ), while the remaining Bi 3+ cations are coordinated by seven O sites. The H 2 O groups in montanite are structurally incorporated into the network of cavities formed by the three-dimensional framework, with other cavity space occupied by the stereoactive 6 s 2 lone pair of Bi 3+ cations. While evidence for a supercell was observed in synthetic montanite, the subcell refinement of montanite adequately indexes all reflections in the PXRD patterns observed in all natural montanite samples analysed in this study, verifying the identity of montanite as a mineral.

Bibliographic Information