Abstract
In-channel water treatment systems remove excess nutrients through biological, chemical, and physical processes associated with the hyporheic zone. However, the impact of surface and groundwater interactions on these treatment processes is poorly understood. This research aims to assess the influence of varying groundwater conditions (neutral, drainage water, and groundwater seepage) and different bed sediment hydraulic conductivities on nitrogen and phosphorus dynamics in in-channel treatment systems. A flume containing bed sediment was used to study changes in surface water quality under different groundwater and bed sediment conditions. Compared to inlet and outlet concentrations, dissolved reactive phosphorus (DRP) and ammoniacal nitrogen (NH 4 -N) levels in the surface water increased by 11–65% and 10–51%, respectively, while nitrate (NO 3 -N) concentrations decreased by 11% under groundwater seepage conditions. The increase in NH 4 -N was due to ammonification, while the decrease in NO 3 -N was due to denitrification and mixing and dilution with the groundwater. The upward groundwater flux through the bed sediment transported both DRP and NH 4 -N into the surface water. Low hydraulic (LH) conductivity sediment led to greater changes in nutrient concentration than high hydraulic (HH) conductivity sediment (DRP increased by 65% and NH 4 -N by 51% for LH, compared to 11% and 10% for HH, respectively). However, HH conductivity sediment led to greater variations in pH and Eh values. The findings could assist the design and monitoring of in-channel treatment systems where groundwater and surface water interact.