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Assessing nonpoint‐source nitrogen loading and nitrogen fixation in lakes using δ 15 N and nutrient stoichiometry

KathiJo Jankowski; Daniel E. Schindler; Gordon W. Holtgrieve
Limnology and Oceanography · Vol. 57, Issue 3 · pp. 671-683 · 2012

Abstract

Runoff from human‐dominated watersheds has greatly altered nitrogen (N) and phosphorus (P) cycling in lakes. Nutrients from human sources are distinct from those from undisturbed ecosystems in several ways including lower N : P ratios, which can drive ecosystems to N‐limited conditions, and enriched stable N isotope ratios. In this study, we used these distinct characteristics to estimate shifts in N sources to 27 lakes across a human density gradient in western Washington. We compared an N stable isotope two‐source mixing model with a mixing model that coupled N stable isotopes to N : P stoichiometry and included N fixation. We found that a two‐source mixing model (human and watershed sources) did not explain observed variation in δ 15 N of particulate organic matter (POM) and primary consumers ( R 2 = 0.60) as well as a model that included a third N source (N fixation; R 2 = 0.72). When fixed N was facultatively added to the ecosystem below a critical N : P ratio, the more complex mixing model captured the observed patterns in POM and primary‐consumer δ 15 N among lakes extremely well. In lakes with P concentrations > 20 µg L −1 (N : P mass ratio 50% of lake N budgets. This model provides a novel way to estimate the contribution of nonpoint N sources and N fixation to lakes in watersheds subject to human nutrient inputs.

Bibliographic Information

JournalLimnology and Oceanography
PublisherWiley
Publication Date2012-05-01
Publication Year2012
Volume57
Issue3
Pages671-683
Document TypeJournal Article
Print ISSN0024-3590
eISSN1939-5590
DOI10.4319/lo.2012.57.3.0671
SubjectAquatic Science

Access Information

NARA Access Coverage1997-01-01~Current
Journal Homepagehttps://aslopubs.onlinelibrary.wiley.com/loi/19395590
Publisher PageOpen Publisher Page
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