Evaluating uncertainties with sample-collection method and source selection in sediment fingerprinting: an example from a Great Lakes tributary

Abstract

Purpose Identifying suspended-sediment (SS) sources, seasonal variability, and phosphorus (P) transported with SS is critical information for basin managers, although there may be concerns about comparability between flow-integrated SS samples used for sediment fingerprinting and discrete samples used for concentrations and loads in basins where SS is mostly silt + clay and(or) one land-use predominates. Objectives were to determine if (1) sample-collection method and (2) source consideration influenced apportionment of the largest SS source. Methods Concurrent-replicate, SS samples were collected during 2022 from the East River, Wisconsin using an automated sampler, commonly used for water-quality sampling, and passive samplers, frequently used for SS fingerprinting. Samples were evaluated for differences in physical and chemical characteristics that may affect source apportionment. Considered sources included three upland land-use (cropland, forest, and roads), two in-channel (streambank and streambed sediment), and one that connects uplands to the stream channel (gullies). Source apportionment used established methods in the SedSAT tool. Source scenarios included land-use + streambank (4src), 4src + gully, 4src + streambed, and 4src + gully + streambed (6src). Results There were no statistically significant differences in median grain size, organic carbon, or sediment-bound P as a function of collection method. In-channel sources were the largest proportional SS source, regardless of season, hydrologic condition, collection method, or source scenario. Source verification highlighted which source fingerprints were most accurately defined and implications for SS target apportionment. Conclusion Varying the source scenarios for sediment fingerprinting indicated that improved management of hydrologic connectivity between upland land use and the stream channel has the potential to mitigate SS loads.

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