Phytochemical studies on the roots, twigs and leaves of Meliaceae and Rutaceae family plants have revealed the presence of non-complex terpenes derived from limonoid fragmentation. The occurrence and chemical structure of these degraded limonoids isolated from 1930 to March 2022 are reported in this review. Particular attention is given to the degradation levels in these compounds and their absolute configuration to discover p...

Summary Trichoderma arundinaceum (Ta37) and Botrytis cinerea (B05.10) produce the sesquiterpenoids harzianum A (HA) and botrydial (BOT), respectively. TaΔTri5, an HA non‐producer mutant, produces high levels of the polyketide compounds aspinolides (Asp) B and C. We analyzed the role of HA and Asp in the B. cinerea ‐ T. arundinaceum interaction, including changes in BOT production as well as transcriptomic changes of BcBOT gene...

Summary H arzianum A ( HA ), a trichothecene produced by T richoderma arundinaceum , has recently been described to have antagonistic activity against fungal plant pathogens and to induce plant defence genes. In the present work, we have shown that a tri5 gene‐disrupted mutant that lacks HA production overproduces two polyketides, aspinolides B and C , which were not detected in the wild‐type strain. Furthermore, four new aspi...