The electrostatic properties of clay (or other charged) mineral surfaces play a significant role in the fate, transport, persistence, and remediation of subsurface contaminant plumes. This study presents a stochastic assessment of the impact and relevance of microscale electrostatic effects on macroscopic, field-scale contaminant transport in heterogeneous groundwater systems involving spatially distributed clay zones. We pres...

Polluted drainage from weathering of sulfide-rich waste rock deposits can cause long-term impairment to waterways and biodiversity near mining sites. Mechanistic models represent established tools to support the predictions of the quantity and quality of waste rock drainage, and their associated risks. Yet, model-based predictions in typical waste rock systems are ubiquitously uncertain because of the strongly heterogeneous na...