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The reduction of NO by CO over a powdered $${\text {Pt/Al}_{2}}\text {O}_3$$ catalyst in flow reactors is investigated as a function of temperature and stoichiometry at low concentrations typical for emission control. The study investigates the initial decline in conversion over pre-reduced catalysts and its correlation with the formation (and decomposition) of isocyanate (–NCO) on the support, tracked by time-resolved operand...
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