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This study presents a comprehensive analysis of gymnodimine-series toxins produced by Alexandrium ostenfeldii (K- 1354) using liquid chromatography tandem mass spectrometry (LC-MS/MS). Three peaks with identical precursor ions but different retention times were observed, suggesting the presence of isomers identified as gymnodimines B, C, and D. Employing an integrated approach combining LC-MS/MS with electron transfer dissocia...